Process for preforming cobaltous salts using shell-type preforme

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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502 28, 568451, 568883, C07C 2720, C07C 31125

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056000316

ABSTRACT:
A process for preparing oxo alcohols and aldehydes by the cobalt catalyzed hydroformylation of C.sub.2 to C.sub.17 linear or branched monoolefins with subsequent hydrogenation of the hydroformylation product, in which oxo process aqueous solutions of cobalt salts are converted to active hydrido cobalt carbonyl species in a preformer reactor under preforming reaction conditions, the improvement characterized by the preformer reactor containing a shell-type, metal on substrate, preformer catalyst.

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Usami et al., "Synthetic Studies of Co Carbonyl by Noble Metal Catalysts. I", Bulletin of the Chemical Society of Japan, vol. 42, pp. 2961-1965 (1969).
Usami et al., "Synthetic Studies of Co Carbonyl by Noble Metal Catalysts. II", Bulletin of the Chemical Society of Japan, vol. 42, 2966-2970 (1969).
"Platinum Metal Review", Johnson Matthey, vol. 38, No. 2, pp. 125-132 (Apr. 1994).

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