Process for preferentially oxidizing sulfides in gold-bearing re

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group ib metal

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423 27, C22B 1100, C01G 700

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active

054588669

ABSTRACT:
A process is provided for recovering gold from refractory sulfide ores. Preferred feed materials have multiple different sulfide mineralogies, with gold being primarily contained within one or more, but not all, of the sulfide mineralogies. Sulfide mineralogies with the highest gold values are preferentially oxidized, while those sulfide mineralogies with relatively little gold remain largely unoxidized. In one embodiment, dissolved arsenic following pressure oxidation is precipitated as ferric arsenate through the control of pH during neutralization. In another embodiment, the oxidized slurry following pressure oxidation is contacted with an oxidizing agent to convert at least a portion of ferrous iron to ferric iron. Following, pressure oxidation, the slurry can be subjected to cyanidation recovery of gold, and liquid from the tailings stream can be recycled upstream of the pressure oxidation step in a substantially untreated form. The process is useful for recovering gold contained as ultra-small masses in sulfide minerals.

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