Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1974-11-11
1977-01-04
Michl, Paul R.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
526209, 526210, 526225, 526317, 526328, 526331, 526347, C08F 3004
Patent
active
040011941
ABSTRACT:
Metallocene that is polymerizable by free radical catalysis and has metal nucleus in a state of oxidation below its maximum can be polymerized without oxidation of such nucleus by forming a reaction mixture containing said metallocene and the reducing agent of a redox catalyst combination, then initiating and maintaining polymerization of said metallocene with the gradual addition of the oxidizing agent of said combination to said reaction mixture.
REFERENCES:
patent: 3063974 (1962-11-01), Pruett
patent: 3238185 (1966-03-01), Neuse
patent: 3350369 (1967-10-01), Rosenberg
patent: 3560429 (1971-02-01), Bilow
patent: 3847871 (1974-11-01), Stephens
Kuwana et al., Chronopotentiometric Studies on the Oxidation of Ferrocene, Ruthenocene, Osmocene, and Some of Their Derivatives, J. Am. Chem. Soc., 82(22), pp. 5811-5817, 1960.
Douthitt Merton H.
Khayat S. I.
Michl Paul R.
SCM Corporation
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