Process for polymerizing cationically polymerizable monomers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S335000, C526S348700

Reexamination Certificate

active

06939933

ABSTRACT:
The invention relates to a new catalyst system that improves the heat transfer capability of a butyl reactor slurry process system in the production of random copolymers of one or more isoolefin monomers and one or more conjugated diene monomers in continuous slurry polymerization processes. The process is carried out in an anhydrous polymerization system containing a mixture of the monomers in a polar diluent along with a Lewis acid and a C5or greater initiator having a tertiary halide.

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Kresge and Wang, “Butyl Rubber,”Kirk-Othmer Encyclopedia of Chemical Technology, 4th Edition, vol. 8, pp. 934-955 (1993), John Wiley & Sons, New York, NY.

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