Process for polymerization of water-soluable and water-insoluabl

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526194, 524558, C08F 2020

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active

057735468

ABSTRACT:
The present invention is directed to an improved process for producing water-soluble and water-insoluble carboxylic acid polymers and copolymers. The process comprises the steps of polymerizing a carboxylic acid monomer, and a polyfunctional cross-linker monomer in a second embodiment, in an effective molar ratio, in a silicone solvent under an inert atmosphere in the presence of an effective amount of an initiator. The preferred copolymer of the second embodiment includes acrylic acid as the carboxylic acid monomer and a lauryl methacrylate and/or stearyl methacrylate as a comonomer. The resulting copolymers have new and unexpected tolerance to salt-containing water when mixed therewith.

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