Process for photographic emulsion precipitation in a recycle str

Gas separation: apparatus – Electric field separation apparatus – Electrode retaining or supporting means

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96 94BF, 961147, G03C 102

Patent

active

041475518

ABSTRACT:
A process for preparing a photographic emulsion having a controlled grain size, structure and size distribution, wherein precipitation of first silver halide grains is accomplished in a stream, and partial substitution in the first silver halide grains of a second soluble halide is accomplished in a vessel by halide conversion to form mixed crystal silver halide grains. The initially formed mixed crystal silver halide grains are recycled in the stream wherein additional precipitation of the first silver halide occurs on the surfaces of the mixed crystals, which are enlarged. The enlarged crystals are fed from the recycle stream to a vessel wherein additional substitution by halide conversion is accomplished. Continuous or intermittent recycling of the mixed crystal silver halide grains, control of recycle flow rates, control of addition flow rates of silver salts and soluble halides to the process and control of excess halide concentration in the conversion vessel and recycle stream yields mixed crystal silver halide grains having a controlled grain size, structure and distribution.

REFERENCES:
patent: 3628959 (1971-12-01), Theielemann et al.
patent: 3705034 (1972-12-01), McNamara
patent: 3782954 (1974-01-01), Porter et al.
patent: 3790386 (1974-03-01), Posse et al.

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