Process for phosphating metal surface to make thereon a zinc pho

Metal treatment – Process of modifying or maintaining internal physical... – Processes of coating utilizing a reactive composition which...

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148262, C23C 2273

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active

053084136

ABSTRACT:
A metal surface is processed with dipping by a first zinc phosphating solution in which a fluoride complex and a simple fluoride are contained and a concentration of this simple fluoride is 200 to 300 mg/l on a basis converted into the HF concentration and that of the fluoride complex is in a mole ratio with the simple fluoride converted into the HF as shown as, [fluoride complex]/[simple fluoride].gtoreq.0.01, and then the surface is processed with spraying by a second zinc phosphating solution in which a simple fluoride concentration is 500 mg/l or less and higher than that in said first zinc phosphating solution.
Thus, on a metal surface is formed a zinc phosphate coating film which is suitable for electrodeposition coating, particular for cationic electrodeposition coating, and superior in coating film adhesion, corrosion-resistance, particularly resistance for warm brine, and prevention of scab-corrosion.

REFERENCES:
patent: 3619300 (1971-11-01), Heller et al.
patent: 3839988 (1974-10-01), Duerr
EP-381-190-A Aug. 8, 1990.

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