Process for oxidizing hydrocyanic acid to cyanogen

Chemistry of inorganic compounds – Nitrogen or compound thereof – Carbon containing

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C01C 300

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039490610

ABSTRACT:
Dicyan is produced by reacting hydrocyanic acid with oxygen or oxygen-containing inert gas in an aqueous solution of copper nitrate or copper nitrate and one or more nitrates of alkali metals, alkaline earth metals or aluminum at a pH of from -0.5 to 1.5. Almost all the small quantity of nitrogen oxides by-produced in the reaction can be removed by absorbing them in the catalyst solution in which the reaction is terminated or retarded and the resulting solution can be reused by recycling.

REFERENCES:
patent: 2953435 (1960-09-01), Fierce et al.
patent: 3494734 (1970-02-01), Nakamura
patent: 3615192 (1971-10-01), Olivier
patent: 3630671 (1971-12-01), Block
patent: 3769388 (1973-10-01), Olivier et al.
Sienko et al., Chemistry, 2nd Edition, 1961, McGraw-Hill Book Company Inc., pp. 497-500.

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