Process for oxidation of hydrocarbons

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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26034832, 26034833, 260545R, 560241, 562412, 562531, 562536, 562545, 568476, 568478, 568557, 568571, 568577, 568836, 568837, C07C 6705

Patent

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042634482

ABSTRACT:
An oxidizable hydrocarbon is oxidized in a reaction zone at elevated temperature in the presence of a liquid reaction medium by introducing the hydrocarbon and a feed stream containing molecular oxygen to the reaction zone under conditions sufficient to oxidize at least a portion of the hydrocarbon; withdrawing at least a portion of the liquid reaction medium from the reaction zone; passing at least a portion of the withdrawn liquid reaction medium to an oxygen injection zone located external to the reaction zone; contacting the liquid in said oxygen-injection zone with a gas stream containing molecular oxygen under conditions sufficient to form a two-phase gas/liquid mixture; and passing said two-phase gas/liquid mixture to the reaction zone as the feed of molecular oxygen thereto.

REFERENCES:
patent: 3584033 (1965-06-01), Copelin
patent: 3692823 (1972-09-01), Gordon
patent: 4189600 (1980-02-01), Weitz

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