Process for oxidation of ammonia

Chemistry of inorganic compounds – Nitrogen or compound thereof – Oxygen containing

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252474, C01B 2126

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active

039313913

ABSTRACT:
Catalysts suitable for the oxidation of ammonia to nitrogen oxides which are suitable to produce nitric acid are prepared by doping cobalt oxide, preferably Co.sub.3 O.sub.4 with 0.1-10 atoms %, preferably 0.5-3 atom % of lithium. In a given case, there is added a mold assist agent to form tablets, spheres, extruded pressed strands or honeycombs. The product is calcined in air or an oxygen stream at 300.degree.-700.degree.C, preferably 400.degree.-600.degree.C and subsequently tempered at 700.degree.-900.degree.C in a reactive gas mixture of air and 8-10 vol. % ammonia to increase the form stability.

REFERENCES:
patent: 3767772 (1973-10-01), Geus et al.
"Chemical Abstracts"; Vol. 67, p. 2478j, 26080j.

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