Process for oxidation of alkanes

Details Process for oxidation of alkanes Process for oxidation of alkanes

2006-08-01

2006-08-01

Witherspoon, Sikarl A. (Department: 1621)

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

C568S910000, C568S910500

Reexamination Certificate

active

07084307

ABSTRACT:
A palladium complex catalyzed process for the oxidation of linear alkanes is proposed which employs molecular oxygen as the oxidant to produce secondary alcohols and ketones in high selectivity, the said catalyst is a single entity and does not requires the use of any co-catalyst or solvent.

REFERENCES:
patent: 5347057 (1994-09-01), Khan
patent: 5393922 (1995-02-01), Sen et al.
patent: 5623090 (1997-04-01), Haruta et al.
Lin et al. A Highly Catalytic System for the Direct Oxidation of Lower Alkanes by Dioxygen in Aqueous Medium. Journal of the American Chemical Socitey, 1992, vol. 114, p 7307-7308.
Lin et al. A Highly Catalytic Bimetallic System for the Low-Temperature Selective Oxidation of Methane and Lower Alkanes with Dioxygen as the Oxidant. Journal of the American Chemical Society, 1997, vol. 119, p 6048-6053.
Rudakov et al. Metallokompleksni Katal., 1977, p 116-129.

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