Process for oxidating hydrocarbons

Details Process for oxidating hydrocarbons Process for oxidating hydrocarbons

1974-02-04

1976-03-23

Morgenstern, Norman

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260586P, 260597R, 260617R, 260617M, 260631R, 260632C, 260632CB, 260631B, C07C 2712, C07C 2716, C07C 2900, C07C 4502

Patent

active

039460770

ABSTRACT:
Hydrocarbons containing from 4 to 20 carbon atoms are oxidized with a gas containing molecular oxygen in the presence of a catalyst and/or auxiliary agents. The resulting reaction mixture is saponified with an aqueous alkaline solution and the resulting alkaline solution containing organic impurities is subjected to liquid phase oxidation with a gas containing molecular oxygen in at least a stoichiometric quantity sufficient for completely burning the organic ingredients, the oxidation taking place in a reaction zone heated to at least 200.degree.C under a pressure sufficient to keep at least some of the water in the liquid phase. The alkali carbonate/bicarbonate solution formed is recycled to the hydrolysis stage.

REFERENCES:
patent: 3232704 (1966-02-01), Helbig et al.
patent: 3243449 (1966-03-01), Winnick
patent: 3316302 (1967-04-01), Steeman et al.
patent: 3796761 (1974-03-01), Marcell et al.

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