Process for organooxylation of cyanoalkylchlorosilanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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C07F 710

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053747577

ABSTRACT:
A process for the organooxylation of .beta.-cyanoalkylchlorosilanes. The process comprises contacting in a film a .beta.-cyanoalkylchlorosilane with an alcohol capable of forming an ester with the silicon of the .beta.-cyanoalkylchlorosilane and thereby forming an equilibrium mixture comprising a (.beta.-cyanoalkyl)organooxysilane and hydrogen chloride. The film is heated at a temperature sufficient to cause vaporization of the hydrogen chloride from the equilibrium mixture thereby increasing yield of (.beta.-cyanoalkyl)organooxysilane in the equilibrium mixture. In a preferred process, the process is run in a falling-film type reactor or a wiped-film type reactor.

REFERENCES:
patent: 4876337 (1989-10-01), Rauleder et al.

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