Process for oligomer production and saturation

Chemistry of hydrocarbon compounds – Plural serial diverse syntheses – With hydrocarbon recycle from later to earlier synthesis

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585254, 585255, 585310, 585315, 585324, 585329, 585330, 585518, 585529, C07C 274, C07C 503, C07C 218

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058116087

ABSTRACT:
A process for the production of saturated oligomers by the oligomerization of light olefins to heavier olefins and the saturation of the heavy olefins is improved by the recycle of the heavy paraffins to the oligomerization zone. The recycle of the heavy paraffins improves the selectivity of the oligomerization for C.sub.8 paraffin products and reduces catalyst fouling. The reduced catalyst fouling can be used to operate the oligomerization zone at lower pressure and facilitate its integration with a dehydrogenation zone for the production of the light olefin stream.

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