Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1991-02-22
1992-08-11
Killos, Paul J.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
C07C 6952
Patent
active
051380927
ABSTRACT:
It comprises reacting, both continuously and discontinuously, acrylic acid and 1-butene in the presence of an ionic exchange resin that contains sulfonic acid groups, carrying out the reaction at a temperature between 50.degree. and 120.degree. C., at a pressure between 10 and 30 kg/cm.sup.2, for a reaction or contact time between 0.5 and 4 hours and using a olefin/acrylic acid molar ratio between 0.3 and 10.
The sec-butyl acrylate obtained is useful in polymerization processes yielding very hard polymers with a high thermal resistance and high resistance to hydrolysis.
FIG. 1 represents a graph of the effect of the olefin/acrylic acid ratio over the conversion of acrylic acid.
Albertos de Benito Fernando
Perez Pascual Miguel A.
Compania Espanola de Petroleos, S.A. Cersa
Killos Paul J.
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