Process for obtaining glycols and glycerine or di- and triesters

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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Details

568858, 560263, C07C 2900, C07C 3120, C07C 3122, C07C 6724

Patent

active

040874532

ABSTRACT:
A process for recovering monomeric glycols and glycerine from polyoxyalkylene glycols and polyglycerines which comprises heating the polymeric compounds together with a lower saturated mono-carboxylic acid, containing from 2 to 4 carbon atoms such as acetic acid, in the presence of a strong acid, e.g. sulfuric acid, or a strong acid cation exchange resin. The product, which is the diester of the monomeric glycol or the triester of glycerine, is recovered and subsequently hydrolyzed to obtain the desired monoglycol or glycerine product. If it is desired to obtain the ester itself, the latter step of hydrolyzing can be omitted.

REFERENCES:
patent: 2030835 (1936-02-01), Cox et al.
patent: 2629735 (1953-02-01), Cottle et al.

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