Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – From nonhydrocarbon feed
Patent
1991-04-09
1992-12-15
McFarlane, Anthony
Chemistry of hydrocarbon compounds
Unsaturated compound synthesis
From nonhydrocarbon feed
585638, 585639, C07C 120
Patent
active
051719207
ABSTRACT:
A process for obtaining a tertiary olefin, e.g. isobutylene in a very pure state by decomposing the corresponding ether, e.g. methyl tert. butyl ether, in the presence of a catalyst constituted by silica, modified by the addition of at least one element or compound of an element preferably chosen from the group constituted by rubidium, cesium, magnesium, calcium, strontium, barium, gallium, lanthanum, cerium, praseodymium, neodymium and uranium and optionally by the addition of at least one element or compound of an element chosen from the group constituted by aluminium, titanium and zirconium.
REFERENCES:
patent: 4254296 (1981-03-01), Manara et al.
patent: 4343959 (1982-08-01), Kida et al.
patent: 4691073 (1987-09-01), Michaelson
Chaumette Patrick
Leporq Serge
Martino Germain
Verdon Catherine
Achutamurthy P.
Institut Francais du Pe'trole
McFarlane Anthony
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