Process for neutralization of petroleum acids (LAW810)

Mineral oils: processes and products – Refining – Organic acid or phenol contaminant removal

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208 47, 208348, C10G 1700

Patent

active

060305231

ABSTRACT:
The present invention describes a process for decreasing the acidity of a starting calcium containing, non-acid treated acidic crude oil by adding such an acidic crude oil to an effective amount of an aqueous base solution at conditions of pH and temperature sufficient to form an unstable emulsion of the acidic crude oil in the aqueous base solution; and breaking the emulsion to form a phase containing treated crude oil having a decreased acidity and aqueous phase residual containing base and neutralized acids. The invention has utility in crude oil processing.

REFERENCES:
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patent: 2068979 (1937-01-01), Fisher
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patent: 5182013 (1993-01-01), Petersen
Petroleum Refining with Chemicals,V.Kalichevsky, 1956,pp. 137-173, Jan. 1956.
Kalichevsky et al, "Petroleum Refining With Chemicals", Elsevier Publishing Company (1956), Chapter 4, pp. 136-180.
Camp et al, "Neutralization as a Means of Controlling Corrosion of Refinery Equipment", Nat'l. Ass'n. of Corrosion Engineers, vol. 6, pp. 39-44.
Scattergood et al, "Naphthenic Acid Corrosion, An Update of Control Methods", Corrosion, Mar. 9-13, 1987, Paper Number 197, pp. 197-1 to 197-5 .

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