Electrolysis: processes – compositions used therein – and methods – Electrolytic coating – Coating predominantly nonmetal substrate
Patent
1995-08-23
1997-12-02
Gorgos, Kathryn L.
Electrolysis: processes, compositions used therein, and methods
Electrolytic coating
Coating predominantly nonmetal substrate
205183, 205125, 205920, C25D 556
Patent
active
056932090
ABSTRACT:
The process for directly metallizing a circuit board having nonconductor surfaces, includes reacting the nonconductor surface with an alkaline permanganate solution to form manganese dioxide chemically adsorbed on the nonconductor surface; forming an aqueous solution of a weak acid and of pyrrole or a pyrrole derivative and soluble oligomers thereof; contacting the aqueous solution containing the pyrrole monomer and its oligomers with the nonconductor surface having the manganese dioxide adsorbed chemically thereon to deposit an adherent, electrically conducting, insoluble polymer product on the nonconductor surface; and directly electrodepositing metal on the nonconductor surface having the insoluble adherent polymer product formed thereon. The oligomers are advantageously formed in aqueous solution containing 0.1 to 200 g/l of the pyrrole monomer at a temperature between room temperature and the freezing point of the solution.
REFERENCES:
patent: 4567250 (1986-01-01), Naarmann et al.
patent: 4869949 (1989-09-01), Muenstedt
patent: 5183552 (1993-02-01), Bressel et al.
Bressel Burkhard
Gedrat Klaus
Meyer Heinrich
Meyer Walter
Atotech Deutschland GmbH
Gorgos Kathryn L.
Mayekar Kishor
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