Process for manufacturing semiconductor, apparatus for manufactu

Compositions – Barrier layer device compositions – Group iii element containing binary compound; e.g. – ga – as

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423413, 501 40, 501 961, 501 964, 501 984, 438 96, H01L 2710

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059763981

ABSTRACT:
A process for manufacturing a semiconductor, including generating a first plasma of a V group element from a V group element source; generating a second plasma of an auxiliary material for activating a metal organic compound containing a III group element separately from and at the same time as the first plasma; adding the vaporized metal organic compound and the plasma of the auxiliary material to the plasma of the V group element; and forming, on a substrate, a film of a semiconductor compound containing the III group element and the V group element. A semiconductor and a semiconductor device having high quality and high functions can be manufactured in a short time at high yield. An amorphous material includes at least hydrogen, a III Group element, preferably gallium, and nitrogen. In the infrared absorption spectrum measured of the amorphous material, the ratio of the absorbance I.sub.N-H, at the absorption peak indicating the bond (N--H) between nitrogen and hydrogen to that, I.sub.C-H, at the absorption peak indicating the bond (C--H) between carbon and hydrogen is 2 or more; and the ratio of the absorbance, I.sub.N-H, at the absorption peak indicating the bond (N--H) between nitrogen and hydrogen to the absorbance, I.sub.III-H, at the absorption peak indicating the bond (III-H) between the III Group element and hydrogen is 0.2 or more.

REFERENCES:
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U. Coscia et. al., "Photoconductivity of amorphous GaAs", Journal of Non-Crystalline Solids, 194 pp. 103-108 (1996).
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Wang et al, "Infrared and Morphological Studies of Hydrogenated AIN Thin Films", Langmuir, vol. 8, pp. 1347-53, 1992 no month.

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