Process for manufacturing N-acyliminodiacetic acids

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2604045, 560153, 560171, 562423, 562518, 562571, 556134, C09F 500, C09F 700, C11C 300

Patent

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045335001

ABSTRACT:
N-acyliminodiacetic acids are manufactured by reacting formaldehyde or a formaldehyde generator compound with a N-unsubstituted amide or a generator thereof and with carbon monoxide in contact with a carbonylation catalyst, for example, a cobalt compound, the ratio of the aldehyde groups to the amide groups being at least 2:1. The formaldehyde generator can be a polymeric form of formaldehyde and the amide generator can be a carboxylic ester, acid or anhydride.

REFERENCES:
patent: 3260745 (1966-07-01), Andress, Jr. et al.
patent: 3766266 (1973-10-01), Wakamatsu et al.
patent: 3904668 (1975-09-01), Gaudette et al.
patent: 4264515 (1981-04-01), Stern et al.

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