Process for manufacturing methyl ketones by oxidation of termina

Details Process for manufacturing methyl ketones by oxidation of termina Process for manufacturing methyl ketones by oxidation of termina

1979-12-18

1982-01-12

Breitenstein, G. T.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568342, 568311, 252429R, C07C 4528

Patent

active

043107044

ABSTRACT:
Methyl ketones are prepared in liquid phase by oxidizing terminal olefins of the formula R--CH.dbd.CH.sub.2, where R is a hydrocarbon radical. The oxidizing agent is hydrogen peroxide or an organic hydroperoxide, and the catalyst is a palladium catalyst of the formula Pd AA', (L.sub.m) where

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Neckers et al., "Organic Chemistry", John Wiley & Son, pp. 1040-1042 (1977).
Cotton et al., "Adv. Inorg. Chem.", Interscience Publ., pp. 753-755 (1972).

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