Process for manufacturing methyl ketones by oxidation of termina

Details Process for manufacturing methyl ketones by oxidation of termina Process for manufacturing methyl ketones by oxidation of termina

1981-05-20

1983-04-12

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568311, C07C 4528

Patent

active

043799426

ABSTRACT:
Methyl ketones are prepared in liquid phase by oxidizing terminal olefins of the formula R--CH.dbd.Ch.sub.2, where R is a hydrocarbon radical. The oxidizing agent is hydrogen peroxide or an organic hydroperoxide, and the catalyst is a palladium catalyst of the formula Pd AA' where

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Wilkinson et al., J. Chem. Soc., pp. 3632-3637 (1965).

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