Process for manufacturing MCM-22 family molecular sieves

Details Process for manufacturing MCM-22 family molecular sieves Process for manufacturing MCM-22 family molecular sieves

2010-08-13

2011-12-20

Brunsman, David M (Department: 1732)

Chemistry of inorganic compounds

Zeolite

Structure defined x-ray diffraction pattern

C423S702000, C423S706000, C208S046000, C208S111010, C208S135000

Reexamination Certificate

active

08080234

ABSTRACT:
A method of manufacturing a molecular sieve of the MCM-22 family, said method comprising the steps of (a) providing a mixture comprising at least one source of ions of tetravalent element, at least one source of alkali metal hydroxide, at least one directing-agent (R), water, and optionally at least one source of ions of trivalent element, said mixture having the following mole composition:Y:X2=10 to infinityH2O:Y=1 to 20OH−:Y=0.001 to 2M+:Y=0.001 to 2R:Y=0.001 to 0.34wherein Y is a tetravalent element, X is a trivalent element, M is an alkali metal; (b) treating said mixture at crystallization conditions for less than 72 hr to form a treated mixture having said molecular sieve, wherein said crystallization conditions comprise a temperature in the range of from about 160° C. to about 250° C.; and (c) recovering said molecular sieve.

REFERENCES:
patent: 4100262 (1978-07-01), Pelrine
patent: 4439409 (1984-03-01), Puppe et al.
patent: 4721806 (1988-01-01), Zinnen
patent: 4721807 (1988-01-01), Zinnen
patent: 4826667 (1989-05-01), Zones et al.
patent: 4873067 (1989-10-01), Valyocsik et al.
patent: 4954325 (1990-09-01), Rubin et al.
patent: 4954663 (1990-09-01), Marler et al.
patent: 4956514 (1990-09-01), Chu
patent: 4956663 (1990-09-01), Gerstch
patent: 4962239 (1990-10-01), Bell et al.
patent: 4962250 (1990-10-01), Dessau et al.
patent: 4962256 (1990-10-01), Le et al.
patent: 4962257 (1990-10-01), Absil et al.
patent: 4968402 (1990-11-01), Kirker et al.
patent: 4973781 (1990-11-01), Valyocsik et al.
patent: 4973784 (1990-11-01), Han et al.
patent: 4982033 (1991-01-01), Chu et al.
patent: 4982040 (1991-01-01), Angevine et al.
patent: 4983276 (1991-01-01), Absil et al.
patent: 4986894 (1991-01-01), Keville et al.
patent: 4992606 (1991-02-01), Kushnerick et al.
patent: 4992611 (1991-02-01), Morrison
patent: 4992615 (1991-02-01), Huss, Jr. et al.
patent: 5000839 (1991-03-01), Kirker et al.
patent: 5001283 (1991-03-01), Altman et al.
patent: 5001295 (1991-03-01), Angevine et al.
patent: 5001296 (1991-03-01), Howley et al.
patent: 5012033 (1991-04-01), Child et al.
patent: 5013422 (1991-05-01), Absil et al.
patent: 5019664 (1991-05-01), Del Rossi et al.
patent: 5019665 (1991-05-01), Partridge et al.
patent: 5019670 (1991-05-01), Le et al.
patent: 5143879 (1992-09-01), Whitehurst
patent: 5164170 (1992-11-01), Rubin
patent: 5236575 (1993-08-01), Bennett et al.
patent: 5240892 (1993-08-01), Klocke
patent: 5250277 (1993-10-01), Kresge et al.
patent: 5362697 (1994-11-01), Fung et al.
patent: 5558851 (1996-09-01), Miller
patent: 5871650 (1999-02-01), Lai et al.
patent: 5895769 (1999-04-01), Lai
patent: 5925330 (1999-07-01), Roth
patent: 6077498 (2000-06-01), Diaz Cabanas et al.
patent: 6099820 (2000-08-01), Miller
patent: 6342200 (2002-01-01), Rouleau et al.
patent: 6936744 (2005-08-01), Cheng et al.
patent: 7011810 (2006-03-01), Dakka et al.
patent: 7799316 (2010-09-01), Lai et al.
patent: 7816573 (2010-10-01), Lai et al.
patent: 7829062 (2010-11-01), Lai et al.
patent: 7842277 (2010-11-01), Roth et al.
patent: 7846418 (2010-12-01), Lai et al.
patent: 8017540 (2011-09-01), Lai et al.
patent: 2004/0030212 (2004-02-01), Al-Soufi et al.
patent: 2007/0191660 (2007-08-01), Johnson et al.
patent: 2007/0191663 (2007-08-01), Johnson et al.
patent: 2010/0147741 (2010-06-01), Lai et al.
patent: 1 296 913 (2001-05-01), None
patent: 1699170 (2005-11-01), None
patent: 3625693 (1988-02-01), None
patent: 0 174 121 (1986-03-01), None
patent: 0 284 206 (1988-09-01), None
patent: 0 293 032 (1988-11-01), None
patent: 0 999 182 (2000-05-01), None
patent: 1 105 348 (2001-03-01), None
patent: 1 249 428 (2002-10-01), None
patent: 1 061 046 (2007-09-01), None
patent: WO 92/12928 (1992-08-01), None
patent: WO 96/01687 (1996-01-01), None
patent: WO 97/17290 (1997-05-01), None
patent: WO 00/06494 (2000-02-01), None
patent: WO 03/006160 (2003-01-01), None
patent: WO 03/006405 (2003-01-01), None
patent: WO 03/029144 (2003-04-01), None
patent: WO 03/093230 (2003-11-01), None
patent: WO 2004/052810 (2004-06-01), None
patent: WO 2005/118476 (2005-12-01), None
patent: WO 2006/015824 (2006-02-01), None
patent: WO 2006/015825 (2006-02-01), None
patent: WO 2006/015826 (2006-02-01), None
patent: WO 2007/094949 (2007-08-01), None
Baerlocher et al., “Atlas of Zeolite Framework Types,” Fifth Ed., 2001.
Corma et al., “Synthesis and characterization of the MCM-22 zeolite”, Zeolite 15 (1995), pp. 2-8.
Guray et al., “Synthesis of Zeolite MCM-22 Under Rotating and Static Conditions”, Microporous and Mesoporous Materials 31 (1999), pp. 241-251.
Inagaki et al., “Textural and Catalytic Properties of MCM-22 Zeolite Crystallized by the Vapor-Phase Transport Method,” Bull. Chem. Soc. Jpn., 77 (2004), pp. 1249-1254.
Kim et al., “Synthesis of Zeolites by Water-Organic Vapor-Phase Transport,” Microporous Materials, 1 (1993), pp. 191-200.
Lok et al., “The Role of Organic Molecules in Molecular Sieve Synthesis,” Zeolites, vol. 3, Oct. 1983, pp. 282-291.
Matsukata et al., “Synthesis of Zeolites Under Vapor Atmosphere, Effect of Synthetic Conditions on Zeolite Structure,” Microporous Materials, 1 (1993), pp. 219-222.
Mochida et al., “The Effects of Seeding in the Synthesis of Zeolite MCM-22 in the Presence of Hexamethyleneimine,” Zeolites 18 (1997), pp. 142-151.
Ravishankar et al., “Characterization and Catalytic Properties of Zeolite MCM-22,” Microporous Materials, vol. 4, Issue 1 (1995), pp. 83-93.
Shu et al., “Methane Dehydroaromatization Over Mo/MCM-22 catalysts: A Highly Selective Catalyst for the Formation of Benzene,” Catalysis Letters 70 (2000), pp. 67-73.
Xu et al., “A Novel Method for the Preparation of Zeolite ZSM-5,” J. Chem. Soc., Chem. Commun. (1990), pp. 755-756.
A. Corma et al., “Delaminated Zeolites: Combining the Benefits of Zeolites and Mesoporous Materials for Catalytic Uses,” Journal of Catalysis, vol. 186, pp. 57-63 (1999).
Baerlocher et al., “Atlas of Zeolite Framework Types,” Elsevier Fifth Revised Edition, 2001.
Doraiswamy et al., “Heterogeneous Reactions: Analysis, Examples, and Reactor Design, vol. 2: Fluid-Fluid-Solid Reactions,” John Wiley & Sons, New York, 1984.
Levenspiel, “Chemical Reaction Engineering,” John Wiley & Sons, 1972.
Marques et al., “Static crystallization of zeolites MCM-22 and MCM-49,” Microporous and Mesoporous Materials, 1999, vol. 32, pp. 131-145.
McCusker, “Product Characterization by X-ray Powder Diffraction,” Verified Syntheses of Zeolite Materials, 2ndRevised Edition, Robson ed, pp. 1-2, (Mar. 2002).
Stiles et al., “Catalyst Manufacture,” Marcel Dekker, New York, 1995.
Szostak, “Molecular Sieves—Principles of Synthesis and Identification,” 2ndedition, Blackie Academic & Professional, London, 1998.
Thomas et al., “Principles and Practice of Heterogeneous Catalysis,” VCH Publishers Inc., 1stedition, 1997.

Affiliated with

Also associated with

Rating

Process for manufacturing MCM-22 family molecular sieves does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for manufacturing MCM-22 family molecular sieves, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for manufacturing MCM-22 family molecular sieves will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-4298592