Etching a substrate: processes – Nongaseous phase etching of substrate – Etching inorganic substrate
Reexamination Certificate
2000-12-07
2004-03-30
Norton, Nadine (Department: 1765)
Etching a substrate: processes
Nongaseous phase etching of substrate
Etching inorganic substrate
C216S013000, C216S017000, C216S041000, C338S0220SD, C338S025000
Reexamination Certificate
active
06712987
ABSTRACT:
BACKGROUND OF THE INVENTION
The invention concerns an electrical resistor, in particular a temperature-dependent measuring resistance with rapid response time, having a conductor path provided with at least two connection contact pads, arranged on an electrically insulating surface of a substrate, wherein a portion of the conductor path spans at least one recess of the substrate in a bridge-like manner, and the conductor path is arranged in a plane. The invention also relates to a process for manufacturing the electrical resistor.
A temperature-dependent measuring resistance with rapid response time is known from German published patent application DE 197 53 642 A1, wherein the resistor is at least partially arranged on an electrically insulating surface of a ceramic substrate, wherein a portion of the conductor path spans in a bridge-like manner a recess situated in the substrate, and the remaining portion of the conductor path is provided with connection contact pads in the edge area of the substrate adjacent to the recess. The conductor path comprises a platinum or a gold layer, wherein the conductor path itself is provided with a cover layer of glass. The connection contact pads are left exposed for the purpose of subsequent contacting. The relatively expensive construction proves to be problematic in this case, especially in view of the structuring of ceramics or glass as a substrate.
Furthermore, a temperature sensor is known from European published patent application EP 0 446 667 A2, which sensor has electrically conducting conductor paths applied in meander form by thin layer technology in a measurement window on an electrically insulating substrate having a low radiation absorption, whose end points are connected to a measurement device circuit. The overall area of the conductor paths in its projection on the plane of the substrate amounts to a 20% coverage ratio of the surface of the measurement window, so that the conductor paths can emit absorbed radiation without interference with other conductor paths. Either the sum of surfaces of the measurement window and the substrate surrounding the measurement window stands in an area ratio of >4:1 to the edge surface bordering the substrate in the measurement window area, or the substrate is substantially etched away under the conductor paths in the measurement window. Then, the cross-sectional area of the reversing bends of the conductor paths lying on the substrate is greater than the cross-sectional area of the conductor paths, so that a resistance action as a consequence of the temperature of the substrate on the conductor path is effectively prevented. With this temperature sensor, temperature measurements in the range of −70 to +50° C. are possible.
Furthermore, a temperature measurement arrangement (radiation thermometer) is known from German published patent application DE 39 27 735 A1, the arrangement having a temperature-sensitive thin layer resistor, which is applied in meander form to a sheet of plastic which is stretched over a hollow in the substrate material. A circuit board or a carrier made of epoxide resin is provided as a substrate. Such a temperature measurement arrangement, owing to the low thermal load capacity, is only suited for use in an environment with temperatures below 200° C.
Still further, from German published patent application DE-OS 23 02 615, a temperature-dependent electrical resistor is known, made of resistance material which forms a coiled conductor path as a thin layer, which is applied to a thin sheet. The sheet, which is made of polymeric plastic, spans with its uncoated side a recess in a carrier element which is made of copper, for example, wherein the recess has the same shape as the conductor path and aligns with it in a direction perpendicular to the sheet plane. The temperature arrangement here is one which requires a high technical expenditure for the requisite precise coverage of conductor path and recess.
From German patent DE 30 15 356 C2, it is known that electric switches in thick layer technology are preferably manufactured on ceramic, plate-shaped substrates by printing of pastes, whose active substances consist of metal powders, glass or glass-ceramic powders, or mixtures of glass and metal oxides. For manufacturing rapidly responding sensors for temperature measurement, temperature-sensitive thick layer resistances are applied to self-supporting layers, which have arisen by paste screen printing with the aid of a filler material which is gasifiable under the effect of temperature, and which cover a subsequently formed hollow space. Here, it is a question of a comparatively expensive process.
Furthermore, from German published patent application DE 38 29 765 A1 or U.S. Pat. No. 4,906,965, a platinum temperature sensor is known, in which a platinum resistance path with at least two ends is applied on a surface of at least one ceramic substrate. For manufacture, a platinum conductor path is applied in the form of a meander zigzag pattern on the inner surface of a ceramic sheet and subsequently shaped into a roll, wherein breaks with alignment bridges are also provided between adjacent points of the conductor path pattern for purposes of alignment. The ceramic substrate is fired together with the applied platinum resistance. The platinum resistance is made resistant to the ambient atmosphere and moisture by sealing measures. In addition, after the alignment the passage openings and conduits requisite for this are also sealed off by means of ceramic coating or glass paste. The comparatively high heat capacity proves to be problematic with such an arrangement, which does not, without more, make possible a rapid response with sudden temperature changes, and reproduces an exact measured value only after completing a transition function.
A further embodiment of a resistor element as rapid temperature sensor is known from German published patent application DE 38 29 195 A1. Here, the resistance element is configured as a layer resistor made of platinum paste, which is accommodated in a bubble made of glass ceramic, which arches over an electrically insulating ceramic substrate. Here, the self-supporting arched resistance layer is seen as problematic in respect to mechanical stresses, such as shock, pressure or vibration, with applications in harsh environments.
SUMMARY OF THE INVENTION
An object of the invention is to create a measuring resistance which has the simplest construction possible, and which can be produced using economical processes. This object is achieved in accordance with the present invention for an electrical resistor in that the substrate is made of metal and is provided with an applied insulation layer as a membrane, wherein the conductor path is arranged on the membrane.
The robust construction proves to be especially advantageous, wherein particularly the security against failure or disturbance has an advantageous effect in consumer goods applications.
In a preferred embodiment of the invention, the conductor path is selectively covered by a passivation layer up to its connection contact pads. It proves to be advantageous herein that the Pt meander, which is manufactured by known photolithographic and PVD processes, is thereby protected from the actions of foreign substances from without and retains its stable resistance value for exact temperature recording.
Furthermore, the substrate advantageously has a thickness in the range of about 0.15 to 0.6 mm, preferably about 0.2 to 0.25 mm. From this there results a particularly rapid response time. Preferably, the metal of the substrate comprises an iron-nickel alloy, preferably FeNi42 (alloy 42). This results in an economical substrate. Moreover, it is possible to use a substrate made of an iron-nickel-cobalt alloy, preferably FeNi28Co18 (VACON 10).
Alternatively, the metal of the substrate can comprise steel 1.4767 (FeCr20Al5). It is also possible to use a substrate of steel 1.4541 or steel 1.4571. Alternatively, an electrical resistor can be used in which the metal of the substrate comprise
Dietmann Stefan
Ullrich Karlheinz
Wienand Karlheinz
Ahmed Shamim
Akin Gump Strauss Hauer & Feld & LLP
Heraeus Electro-Nite International N.V.
Norton Nadine
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