Process for manufacturing alkylphosphonate monoesters

Solid anti-friction devices – materials therefor – lubricant or se – Lubricants or separants for moving solid surfaces and... – Organic phosphorus compound – wherein the phosphorus is...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C558S117000

Reexamination Certificate

active

10439751

ABSTRACT:
The present invention discloses a process for manufacturing an alkylphosphonate monoester. The process may comprise partially hydrolyzing an alkyl phosphonate diester with an alkaline compound in a first solvent to provide a reaction mixture, wherein the first solvent comprises a mixture of an alcohol and water. The reaction mixture may be diluted with a second solvent to provide an organic phase, wherein the second solvent comprises at least one non-polar organic solvent. The process may comprise acidifying the reaction mixture with an acid, wherein the organic phase includes an alkylphosphonate monoester.

REFERENCES:
patent: 2784208 (1957-03-01), Ries et al.
patent: 3778375 (1973-12-01), Braid et al.
patent: 3798162 (1974-03-01), Dickert et al.
patent: 3927232 (1975-12-01), Dickert et al.
patent: 5302707 (1994-04-01), Campbell et al.
patent: 5359115 (1994-10-01), Campbell et al.
patent: 5420328 (1995-05-01), Campbell
patent: 5910469 (1999-06-01), Carey et al.
patent: 85 1 00469 (1986-01-01), None
patent: 1 807 924 (1969-06-01), None
patent: 2 551 598 (1977-04-01), None
patent: 1 247 541 (1971-09-01), None
patent: 1 559 883 (1980-01-01), None
Horiuchi, Kiyoshi; Okamoto, Yoshiki; Sakurai, Hiroshi; “Synthesis and properties of Monoethyl n-alkylphosphonates,” Kogyo Kagaku Zasshi; (1967), 70(7), 1261-2.
Hu, Wen-Xiang et al., “Synthesis of Mono-Ester of Alkylphosphonates,” Acta Chemica Sinica, 1996, 54, pp. 77-83.
Gaboyard, M. et al., “Synthese et Etude Structurate D'Acides Alkylphosphoniques a Longue Chaine Hydrocarbonee,” Phosphorus, Sulfur and Silicon, 2002, vol. 177, pp. 877-891.
Christol, Henri et al., “Hydrolyse Basique de Phosphonates I. Etude Qualitative,” Journal of Organometallic Chemistry, 12, 1968, pp. 459-470.
Christol, Henri et al., “Hydrolyse Basique de Phosphonates II. Etude Quantitative,” Journal of Organometallic Chemistry, 12, 1968, pp. 471-476.
Boutevin, B. et al., “Monodealkylation of Phosphonic Esters, Synthesis of Phosphonic Salts and Monoacids,” Phosphorus, Sulfur and Silicon, 2001, vol. 174, pp. 1-14.
Saady, Mourad et al., “Selective Monodeprotection of Phosphate, Phosphite, Phosphonate and Phosphoramide Benzyl Esters,” J. Org. Chem, 1995, 60, pp. 2946-2947.
Pienaar, Andre et al., “Synthesis of Alkyl Hydrogen Alkylphosphonates,” Phosphorus, Sulfur and Silicon, 1999, vol. 148, pp. 149-159.
Hu, Wen Xiang et al., “Synthesis of Hindered Alkyl Phosphonates and Phosphonic and Phosphinic Acids,” Chinese Chemical Letters, 1992, vol. 3, No. 3, pp. 167-170.
Pietzonka, et al., “Phosphonate-Containing Analogs of Cholesteryl Ester as Novel Inhibitors of Cholesteryl Ester Transfer Protein,” Bioorganic & Medicinal Chemistry Letters, vol. 6, No. 16, 1996, pp. 1951-1954.
Chemical Abstracts; Yuan, Chengye et al: “Studies on organophosphorus compounds. XXIV. Synthesis of monobutyl esters of octylphosphonates;” XP002292189; retrieved from STN Database accession No. 1989:95370 “abstract” Huaxue Xuebao, 46(3), 290-3 CODEN: HHHPA4; ISSN: 0567-7351, 1988.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Process for manufacturing alkylphosphonate monoesters does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for manufacturing alkylphosphonate monoesters, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for manufacturing alkylphosphonate monoesters will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3779481

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.