Process for manufacture of quaternary ammonium tosylate...

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

Reexamination Certificate

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C564S134000, C564S142000

Reexamination Certificate

active

11128980

ABSTRACT:
An efficient, simple, high yielding, eco-friendly process for the manufacture of tosylates quaternary ammonium salts of cinnamidoalkylamines and/or benzamidoalkylamines (Formula I) has been described. These compounds are substantive UV-absorbers. They are useful in making fabric care products and personal care products.The scope of this methodology has been demonstrated by converting water soluble organic sunscreen quaternary halides to their corresponding tosylates of Formula VI.

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patent: 5451394 (1995-09-01), Chaudhuri et al.
patent: 6426435 (2002-07-01), Koshti et al.
patent: 6613340 (2003-09-01), Koshti et al.
Jachowicz et al., Photodegredation of hair and its Photoprotection by a substantive Photofilter, Drug and Cosmetic Industry, (1995), 157 (6), 28, 30, 32, 35-6, 38, 40, 42, 44.
Anselmi et al., Conformation and Dynamics in a Solution of an N-Quatermized Cinnamide Derivative: a molecule active as a UV filter, Magnetic Resonance in Chemistry (1992), 30 (10), 944-9.

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