Process for manufacture of linear alpha-olefins using a titanium

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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585511, 585512, 585513, 585514, 585515, 585521, 585526, 585528, 585532, C07C 202, C07C 224

Patent

active

061215023

ABSTRACT:
A process for the manufacture of linear alpha-olefins is disclosed. The process employs, for the purposes of oligomerizing an unsaturated aliphatic hydrocarbon to linear alpha-olefins, a catalyst mixture comprising titanium aryl and/or titanium alkoxide, organoaluminum halide and optionally one or more additives selected from a group containing phosphorus, oxygen and sulphur compounds.

REFERENCES:
patent: 4689437 (1987-08-01), Murray
patent: 4737479 (1988-04-01), Frame et al.
patent: 4870041 (1989-09-01), White
patent: 5146028 (1992-09-01), Job

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