Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing
Patent
1992-12-23
1994-01-25
Shaver, Paul F.
Organic compounds -- part of the class 532-570 series
Organic compounds
Silicon containing
C07F 716
Patent
active
052817393
ABSTRACT:
The present invention is an improvement of the Direct Process for the manufacture of alkylhalosilanes by the contact of powdered metallurgical grade silicon with an alkyl halide in the presence of a copper catalyst. The improvement reduces lot-to-lot variations in silicon conversion to desired dialkyldihalosilanes. The improvement comprises alloying 0.01 to nine weight percent copper with the silicon to be used in the process and separating slag. In a preferred embodiment of the present process, silicon-copper alloy is pulverized to a powder and mixed with additional copper and other catalysts to form a contact mass reactive with alkylhalides.
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Halm Roland L.
Kuivila Charles S.
Zapp Regie H.
Boley William F.
Dow Corning Corporation
Shaver Paul F.
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