Process for making polycarboxylic acids

Chemistry: molecular biology and microbiology – Micro-organism – tissue cell culture or enzyme using process... – Preparing oxygen-containing organic compound

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435134, 435145, 4351721, 4351723, 43525222, 435924, C12P 744, C12P 746, C12P 764

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active

059622857

ABSTRACT:
Aliphatic polycarboxylic acids are made by a process comprising the steps of: (1) fermenting a beta-oxidation blocked C. tropicalis cell wherein both copies of the chromosomal POX5 gene and the chromosomal POX4A and POX4B genes are disrupted in a culture medium comprised of a nitrogen source, an organic substrate and a cosubstrate wherein the substrate is an unsaturated aliphatic compound having at least one internal carbon--carbon double bond and at least one terminal methyl group, a terminal carboxyl group and/or a terminal functional group which is oxidizable to a carboxyl group by biooxidation; (2) reacting the product of step (1) with an oxidizing agent to produce one or more polycarboxylic acids.

REFERENCES:
patent: 2450858 (1948-10-01), Fitzpatrick et al.
patent: 2813113 (1957-11-01), Goebel et al.
patent: 5254466 (1993-10-01), Picataggio et al.
patent: 5470741 (1995-11-01), Oester et al.
patent: 5620878 (1997-04-01), Picataggio et al.

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