Process for making phenoxycycloalkanols

Details Process for making phenoxycycloalkanols Process for making phenoxycycloalkanols

1986-02-19

1988-06-28

Mars, Howard T.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568606, 568646, 568670, C07C 4103

Patent

active

047540761

ABSTRACT:
A process for producing a phenoxycycloalkanol comprising reacting an aromatic alcohol with an (optionally substituted) C.sub.5 -C.sub.6 cycloalk-1,2-ylene oxide in the presence of an effective amount of a sodium-containing catalyst selected from the group consisting of sodium metal, C.sub.1 -C.sub.8 sodium alkoxide, C.sub.6 -C.sub.10 sodium aryloxide, C.sub.7 -C.sub.9 sodium alkaryloxide and sodium hydride at between about 170.degree. C. and about 225.degree. C.

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Posner et al, Jour. Amer. Chem. Soc. 99 (1977) 8208, 8214-8218.
Rowton et al, J. Org. Chem. 23, 1057 (1958).

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