Process for making norpatchoulenol and novel intermediates usefu

Details Process for making norpatchoulenol and novel intermediates usefu Process for making norpatchoulenol and novel intermediates usefu

1980-09-22

1982-05-04

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

C07F 718

Patent

active

043283527

ABSTRACT:
A novel norpatchoulenol synthesis is disclosed. The key step in the synthesis is an intramolecular Diels-Alder condensation of a trisubstituted silyloxy derivative of cyclohexadienone. Novel intermediates, namely trisubstituted silyloxy methanonaphthalenes (Formula V, infra) and trisubstituted silyloxy cyclohexadienes (Formula IV, infra) are prepared.

REFERENCES:
patent: 4077996 (1978-03-01), Sauer et al.

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