Process for making monomenthyl esters

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

Reexamination Certificate

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C560S188000

Reexamination Certificate

active

11363446

ABSTRACT:
A process for making monomenthyl esters of dicarboxylic acids is disclosed. Menthol reacts with a saturated, cyclic anhydride in the presence of a base catalyst under conditions effective to produce a mixture of mono- and bis-menthyl esters in which the molar ratio of mono- to bis-menthyl esters is enhanced compared with the ratio of esters produced in a similar uncatalyzed process.

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Takeshi Shimizu, Ryoichi Kobayashi, Hiromichi Ohmori, Tadashi Nakata□□Synthesis of Dicarboxylic Monoesters with Cyclic Anhydrides under High Pressure.□□SYNLETT, pp. 650-652, Jun. 1995.
Dr. Junzo Otera□□Esterification, 2003, pp. 91-123.□□Wiley-VCH Verlag GmbH & Co. KGaA.
Takeshi Shimizu, Ryoichi Kobayashi, Hiromichi Ohmori, Tadashi Nakata□□Synthesis of Dicarboxylic Monoesters with Cyclic Anhydrides under High Pressure.□□SYNLETT, pp. 650-652, Jun. 1995.
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T. Shimizu et al.,Synlett(1995) 650.

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