Process for making high-performance polyethylene...

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Reexamination Certificate

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C428S364000, C428S394000

Reexamination Certificate

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07618706

ABSTRACT:
The invention relates to a process for making high-performance polyethylene multi-filament yarn comprising the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolidof at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dnand length Dnwith Ln/Dnof from 0 to at most 25, to result in a draw ratio DRfluid=DRsp*DRagof at least 150, wherein DRspis the draw ratio in the spinholes and DRagis the draw ratio in the air-gap, with DRspbeing greater than 1 and DRagat least 1. The invention further relates to a high-performance polyethylene multifilament yarn, and to semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites.

REFERENCES:
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patent: 5068073 (1991-11-01), Pennings et al.
patent: 5740451 (1998-04-01), Muraki et al.
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patent: 1432077 (2003-07-01), None
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patent: 0 200 547 (1986-11-01), None
patent: WO 94/12703 (1994-07-01), None
patent: WO 01/73173 (2001-10-01), None
Patent Abstract of Japan, vol. 005, No. 128, Aug. 18, 1981 & JP 56 063004 A, May 29, 1981.
International Search Report.

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