Process for making copolymers of aromatic vinyl compounds ADD co

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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525237, 526 87, 526 89, 526340, C08L 906, C08L 5302

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active

049488490

ABSTRACT:
There are disclosed copolymers of aromatic vinyl compounds, e.g., styrene, and conjugated diolefins, e.g., butadiene, possessing a differential content of the aromatic vinyl compound such that in at least one of the end portions of the copolymer the differential content shows a sharp and substantial increase in the direction of the outer extremity of the end portion. Preferred compolymers are styrene-butadiene copolymers having a vinyl content of at least 30%. In special embodiments, the copolymer have a styrene content changing in a portion of no more than 5% of the copolymer chain from a first value to a second value, the second value being at least 25 percentage points greater than the first value, and the portion is present within a 10% terminal portion of the copolymer. The copolymers are useful in the tread portions of tires as tires containing such copolymers in the tread composition have improved rolling resistance and/or grip on wet road surfaces.

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patent: 3953543 (1976-04-01), Futamura et al.
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patent: 4105714 (1978-08-01), Trepka et al.
patent: 4334567 (1982-06-01), Bond
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Plaste und Kautschuk, Paper of Gomoll and Seide, 16 JG, H.6,1969 S 412-415.
Journal of Polymer Science, Part A-1, vol. 10, pp. 1319-1334 (1972).
Stereospecific Rubbers, Ed. U. Soltmen, Moscow "Mir" 1984, page 279.

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