Process for making catalytically active aluminosilicates and the

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – From nonhydrocarbon feed

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585408, 585469, 585733, 502 64, 502 71, 423334, C07C 120

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044711484

ABSTRACT:
The disclosure relates to a process for making catalytically active aluminosilicates from glasses by hydrothermal cristallization. The hydrothermal cristallization is more particularly effected in the presence of an aqueous solution of an inorganic alkali metal compound producing an alkaline reaction but in the absence of an amine. Useful alkali metal compounds comprise alkali metal carbonate, water glass, alkali metal hydroxide or alkali metal phosphate.
The catalytically active aluminosilicates can be used for dehydrating alcohols, ethers and other oxygen-containing organic compounds with formation of hydrocarbons, or for isomerizing or alkylating hydrocarbons.

REFERENCES:
patent: 3252757 (1966-05-01), Granquist
patent: 3359068 (1967-12-01), Michalko
patent: 4333859 (1982-06-01), Vaughan et al.
R/o/ mpps-Chemie-Lexicon, 8th Edition, ed. by Otto-Albrecht Neum/u/ ller, Frankh'sche Verlagshandlung, W. Keller & Co., Stuttgart, 1979, p. 498.
Howley, "Condensed Chemical Dictionary", (Van Nostrand, 1977), pp. 122 and 413.

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