Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1989-04-18
1991-05-28
Killos, Paul J.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
2604055, 568341, C09F 708, C11L 314
Patent
active
050192973
ABSTRACT:
Olefinically unsaturated secondary alcohols in which the carbon-carbon double bond and the alcohol functionality are separated only by methylene groups are isomerized to ketones by reacting a mixture composed of an olefinically unsaturated secondary alcohol and a catalyst effective amount of a substantially fully hydrogenated palladium catalyst at a temperature of from about 200.degree. C. to about 300.degree. C. and passing hydrogen through the reaction mixture until the iodine number of said reaction mixture is less than 10 and separating the catalyst from the ketone.
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Journal of the American Oil Chemists Society, vol. 42, pp. 340-344 (1965).
Journal of Oil, Technologists Assoc. of the India, pp. 61-64 (Jul./Sep. 1976).
Henkel Research Corporation
Killos Paul J.
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