Process for isolation of desired isomers of nebivolol...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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Reexamination Certificate

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07858812

ABSTRACT:
The present invention relates to a simple and commercially viable process for separation of desired isomers of nebivolol intermediates from a mixture containing undesired isomers of nebivolol intermediates. Thus, (+)-[2R*[1S*,5S*(S*)]]+[2R*[1S*,5R*(R*)]]-α,α′-[phenylmethyliminobis(methylene)]bis[6-fluoro-3,4-dihydro-2H-1-benzopyran-2-methanol] is dissolved in diisopropyl ether at reflux temperature and cooled to below about 30° C. to obtain the desired (+)-[2R*[1S*,5S*(S*)]]-α,α′-[phenylmethyliminobis(methylene)]bis[6-fluoro-3,4-dihydro-2H-1-benzopyran-2-methanol].

REFERENCES:
patent: 5759580 (1998-06-01), Jans et al.
patent: 0145067 (1985-06-01), None
patent: 0334429 (1989-09-01), None
patent: WO 2006/016376 (2006-02-01), None
H.Y. Aboul-Enein and I. Ali, HPLC Enantiomeric Resolution of Nebivolol on Normal and Reversed Amylose Based Chiral Phases, Pharmaceutical Analysis Laboratory, Biological and Medical Research Department, King Faisal Specialist Hospital and Research Centre, Riyadh, Saudi Arabia, (2001), 56(3), 214-216, Supplied by the British Library—The World's Knowledge.
PCT Notification of Transmittal of the International Search Report and the Written Opinion of the International Searching Authority, or the Declaration dated Jan. 18, 2006.

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