Process for increasing the cetane index of distillate obtained f

Mineral oils: processes and products – Chemical conversion of hydrocarbons – With preliminary treatment of feed

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208 15, 208157, 208216PP, 208251H, C10G 1105, C10G 6512

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active

044154364

ABSTRACT:
A metal- and/or sulfur contaminated charge stock containing residua is hydrotreated in a first reaction zone in the presence of a hydrotreating catalyst comprising a hydrogenating component selected from the Group VIB and Group VIII metals, preferably a combination of nickel and molybdenum, on a refractory support, preferably alumina or silica-alumina, to reduce the metal and/or sulfur content thereof, the demetalated and/or desulfurized residua is hydrocracked in a second reaction zone in the presence of a hydrocracking catalyst comprising a nickel and tungsten impregnated rare earth exchanged zeolite X in combination with a nickel and tungsten impregnated silica-alumina matrix to provide distillate of higher cetane index than that achieved with hydrotreatment alone, and the liquid effluent from said second reaction zone is thereafter passed to a third reaction zone containing a hydrotreating catalyst which is the same as, or is different from, the hydrotreating catalyst in the first reaction zone to effect further hydrotreatment.

REFERENCES:
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patent: 3882049 (1975-05-01), Bertolacini et al.
patent: 4054508 (1977-10-01), Milstein et al.
patent: 4183801 (1980-01-01), Breuker et al.
patent: 4197184 (1980-04-01), Munro et al.
patent: 4344840 (1982-08-01), Kunesh

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