Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1996-08-26
1997-09-30
Dees, Jose G.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
5689098, 568815, C07C 2948, C07C 3102, C07C 2710
Patent
active
056727780
ABSTRACT:
The invention comprises a method for the catalytic conversion of alkanes and alkylhydroperoxides to oxygenates, particularly alcohols, comprising the oxidation of alkanes to yield alkylhydroperoxides, alcohols, other reaction products and unreacted alkane, and the decomposition of said alkylhydroperoxides to form alcohols and oxygen. Decomposition of the alkylhydroperoxide in the presence of unreacted alkane increases the yield of alcohol. The process further comprises drying of the reaction mixture comprising alkylhydroperoxide. Suitable catalysts for the process of the invention comprise metal containing catalysts, including metal organic ligand catalysts such as unsubstituted and substituted metal complexes of porphyrins, phthalocyanines and acetylacetonates.
REFERENCES:
patent: 3879467 (1975-04-01), Zajacek
patent: 5004837 (1991-04-01), Baur
Bhinde Manoj V.
Ellis, Jr. Paul E.
Lyons James E.
Dees Jos,e G.
Dickinson Q. Todd
Falk Stephen T.
Sun Company, Inc. (R & M)
Vollano Jean F.
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