Process for improving the quality of epitaxial silicon films gro

Metal treatment – Process of modifying or maintaining internal physical... – Chemical-heat removing or burning of metal

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29576E, 29576T, 148 15, 148189, 148191, 148DIG3, 148DIG117, 148DIG150, 156612, 156613, 156614, 156DIG64, 156DIG73, 156DIG95, 357 4, 357 49, H01L 2120, H01L 2176

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046611762

ABSTRACT:
The present invention accomplishes the thermal oxidation of the silicon side of the interface present in epitaxial silicon films grown on yttria-stabilized cubic zirconia, <Si>/<YSZ>, to form a dual-layer structure of <Si>/amorphous SiO.sub.2 /<YSZ>. The SiO.sub.2 films are formed in either dry oxygen (at 1100.degree. C.) or in pyrogenic steam (at 925.degree. C.) by the rapid diffusion of oxidizing species through a 425 .mu.m thick cubic zirconia substrate. For instance, a 0.17 .mu.m thick SiO.sub.2 layer is obtained after 100 min in pyrogenic steam at 925.degree. C. This relatively easy transport of oxidants is unique to YSZ and other insulators which are also superionic oxygen conductors, and cannot be achieved in other existing Si/insulator systems, such as silicon-on-sapphire.

REFERENCES:
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patent: 4447497 (1984-05-01), Manasevit
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Manasevit et al., "Si on Cubic Zirconia", J. Electrochem. Soc., vol. 130, No. 8, Aug. 1983, pp. 1752-1757.
Golecki et al., "Heteroepitaxial Si Film . . . Zirconia Substrates", Appl. Physics Letters, vol. 42, No. 6, Mar. 15, 1983, pp. 501-503.
I. Golecki "The Current Status of Silicon-on-Sapphire and Other Heteroepitaxial Si-on-Insulator Technologies", presented at the Spring Meeting of the Materials Research Society, Albuquerque, New Mexico, Feb. 1984.
I. Golecki, H. M. Manasevit "Oxidation Through the Zirconia Substrate of Ytria-Stabilized Cubic Zirconia", presented at Electronic Materials Conference Materials Conference Jun. 20-22, 1984, Santa Barbara, Calif.--describes invention, submitted for publication to Journal of Electronic Materials in Feb. 1985.
D. Pribat et al., "Heteroepitaxial Growth of Silicon on (100) Ytria-Stabilized Zirconia (YSZ) and Thermal Oxidating of the Si-YSZ Interface", Material Letter 2,524 (Sep. 1984)--publication describing substance of Hum patent application by others.
L. M. Mercandelli et al., "Epitaxial Silicon on Ytria-Stabilized Cubic Zirconia (YSZ) and Subsequent Oxidation of the Si/YSZ Interface," Material Research Soc. Conference, Boston, 1984 (Nov.) paper #D.3.12.
M. Duprey "Observations en Microscopic Electronique en Transmission de Coupes Transversales, Minces pour des Applications en Microelectronique", J. Microsc Spectrosc. Electron 9, 163 (1984).
I. Golecki "Alternate Substrate Material: Silicon on Ytria Stabilized Cubic Zirconia (Si/YSZ)", Final Report AFWAL-TR-83-4137 Jan. 1984.

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