Process for hydrolyzing stereoisomer esters of trans chrysanthem

Chemistry: molecular biology and microbiology – Process of utilizing an enzyme or micro-organism to destroy... – Resolution of optical isomers or purification of organic...

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435136, C12P 4100

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active

052815340

ABSTRACT:
Chrysanthemic acid esters can be geometrically separated into its cis- and trans- isomers as well as resolved into enantiomers by hydrolysis using liver enzymes, particularly from sheep, goat, bovine, dog, chicken, mouse, calf, horse, pigeon, rabbit, cat, whale and rat and particularly horse.

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Abernathy, CA 80: 606d c1974).
Mitsuta et al., CA 110:113240m (Mar. 27, 1989).
Soderlund et al., CA 87:129395h (1978).
Soderlund, Pest. Biochem & Physiology, 7, 391-401 (1977).
Schneider et al., Angew. Chem. Int. Ed. Eng. 23, (1984).
Sigma Catalog, pp. 952-953, 584 (1989).
Abernathy Co., Pesticide Biochem. Physiol 3:300-11 (1973).
Klibanov AM, TIBS 14:141-144 (1989).

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