Process for hydrolyzing 2,6-dideoxy-2,6-iminoheptononitrile deri

Details Process for hydrolyzing 2,6-dideoxy-2,6-iminoheptononitrile deri Process for hydrolyzing 2,6-dideoxy-2,6-iminoheptononitrile deri

1988-07-01

1989-11-14

Foelak, Morton

Organic compounds -- part of the class 532-570 series

Organic compounds

Carbohydrates or derivatives

536 179, C07H 1500, C07H 1700, C07H 1702

Patent

active

048809179

ABSTRACT:
A procedure for the mild conversion of a carbonitrile to the corresponding carboxylic acid by first using trifluoroacetic acid in the presence of a catalytic amount of mercuric ion followed by oxidative hydrolysis with dinitrogen tetroxide is described herein. The use of this procedure in the preparation of 1,3,4,5-tetra-O-benzoyl-2,6-dideoxy-2,6-imino-D-glycero-L-gulo-heptitol hydrochloride is also described here.

REFERENCES:
patent: 4634765 (1987-01-01), Liu
patent: 4639436 (1987-01-01), Junge et al.

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