Process for hydrogenation of aromatics in hydrocarbon...

Chemistry of hydrocarbon compounds – Adding hydrogen to unsaturated bond of hydrocarbon – i.e.,... – Hydrocarbon is aromatic

Reexamination Certificate

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C585S269000

Reexamination Certificate

active

11397063

ABSTRACT:
The present invention relates to an improved process for the hydrogenation of aromatics in hydrocarbon feedstocks containing thiopheneic compounds as impurities, the aromatics hydrogenation being conducted in a hydrogenation reactor in the presence of a nickel based catalyst. The improvement comprises operating the hydrogenation reactor at a reaction temperature sufficiently high from the start of a run, that the thiopheneic compounds are decomposed and substantially absorbed into the bulk of the nickel catalyst, thereby substantially extending the life of the catalyst.

REFERENCES:
patent: 2101104 (1937-12-01), Smith et al.
patent: 3234298 (1966-02-01), Van Zijil Langhout et al.
patent: 3472763 (1969-10-01), Nanterre et al.
patent: 3674707 (1972-07-01), Pieters et al.
patent: 3700742 (1972-10-01), Hayes
patent: 3714030 (1973-01-01), Winsor et al.
patent: 3755148 (1973-08-01), Mickelson
patent: 3775506 (1973-11-01), Houston, Jr. et al.
patent: 3793388 (1974-02-01), Pitzer
patent: 3798279 (1974-03-01), Cessou et al.
patent: 3856831 (1974-12-01), Tateishi et al.
patent: 3859370 (1975-01-01), Carter et al.
patent: 3899543 (1975-08-01), Cosyns et al.
patent: 4098683 (1978-07-01), Conway
patent: 4118342 (1978-10-01), Debus et al.
patent: 4160745 (1979-07-01), Murrell et al.
patent: 4249907 (1981-02-01), Callejas
patent: 4327234 (1982-04-01), Nowack et al.
patent: 4361705 (1982-11-01), Marcelin et al.
patent: 4695560 (1987-09-01), Gattuso et al.
patent: 4716256 (1987-12-01), Johnson et al.
patent: 4734540 (1988-03-01), Gattuso et al.
patent: 4761510 (1988-08-01), Naruse et al.
patent: 4920089 (1990-04-01), Van Beek et al.
patent: 4973785 (1990-11-01), Lok et al.
patent: 5081083 (1992-01-01), Wright
patent: 5095160 (1992-03-01), Penella et al.
patent: 5189233 (1993-02-01), Larkin et al.
patent: 5277794 (1994-01-01), Delaney et al.
patent: 5451312 (1995-09-01), Apelian et al.
patent: 5482616 (1996-01-01), Brahma et al.
patent: 5773670 (1998-06-01), Gildert et al.
patent: 5856603 (1999-01-01), Rekker et al.
patent: 5954948 (1999-09-01), Galperin
patent: 6197721 (2001-03-01), Didillon et al.
patent: 7081555 (2006-07-01), Himelfarb et al.
patent: 2002/0188161 (2002-12-01), Kallenbach
patent: 0731156 (1996-09-01), None
patent: 1412155 (1973-05-01), None
patent: 2139843 (1999-10-01), None
patent: WO 96/37168 (1998-08-01), None
“Deactivation of Fixed-Bed Nickel Hydrogenation Catalysts by Sulfur,” by E.K. Poels in Fuel 1995, vol. 74, No. 12, 1995, no month.
Seoane, X.L., Arcoya, A., Gonzalez, J. A., and Travieso, N., Hydrogenation of Ethylbenzene over a Nickel/Mordenite Catalyst. Catalytic Decay by Thiophene Poisoning,Ind. Eng. Chem. Res.1989, 28, pp. 260-264, no month.
Marécot, P., Paraiso, E., Dumas, J.M., and Barbier, J., “Deactivation of Nickel Catalysts by Sulphur Compounds I. Benzene Hydrogenation,”Applied Catalysis A: General, 80 (1992) pp. 79-88, no month.
Marécot, P., Paraiso, E., Dumas, J.M., and Barbier J., Deactivation of Nickel Catalysts by Sulphur Compounds II. Chemisorption of Hydrogen Sulphide,Applied Catalysis A: General, 80 (1992) pp. 89-97, no month.
International Search Report of Dec. 16, 2003.

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