Process for hydrogen sulfide production

Chemistry of inorganic compounds – Sulfur or compound thereof – Binary compound

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Details

423563, 423415A, 423443, C01B 1716, C01B 3126

Patent

active

041465806

ABSTRACT:
A hydrocarbon is partially oxidized in the presence of steam and oxygen in a high temperature reducing flame zone to which sulfur is added in excess of the quantity of hydrogen and carbon monoxide formed to generate a second flame zone. The gas stream is rapidly cooled to prevent further reactions, then further cooled to condense sulfur to the extent of providing unreacted hydrogen and carbon monoxide in a molar excess over the residual sulfur present in the gas stream. The resultant gas stream is passed to a catalytic conversion zone where residual sulfur and carbonyl sulfide are converted to hydrogen sulfide. A formed gas stream free of sulfur and sulfur dioxide may be cooled to below the dew point of water to remove water prior to use.

REFERENCES:
patent: 1173566 (1916-02-01), Carner et al.
patent: 3579302 (1971-05-01), Sefton
patent: 3961035 (1976-06-01), Mickley
patent: 4094961 (1978-06-01), Beavon

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