Process for hydrogen production from hydrogen sulfide dissociati

Chemistry of inorganic compounds – Sulfur or compound thereof – Elemental sulfur

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4236481, 20415719, 20415752, C01B 1704, C01B 304

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active

058433953

ABSTRACT:
A process using high-temperature thermal dissociation to recover hydrogen and salable sulfur from industrial waste streams containing hydrogen sulfide (H.sub.2 S) is disclosed. Thermal dissociation occurs in a thermoelectric reactor at temperatures up to 1900.degree. C. Waste energy from the high-temperature reactor is recovered and used to preheat the H.sub.2 S-laden stream before entering the high-temperature reactor. Sulfur is separated out in a condenser. The process also includes a scrubber to eliminate the carryover of liquid sulfur mists or aerosols, and a membrane to separate the hydrogen from the dissociated product stream. Trace amounts of unconverted H.sub.2 S are recycled through the process for further dissociation.

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