Process for hydrocarbonylations in supercritical carbon dioxide

Details Process for hydrocarbonylations in supercritical carbon dioxide Process for hydrocarbonylations in supercritical carbon dioxide

1998-03-27

1999-10-05

Geist, Gary

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568451, 568840, 568909, 568850, 568882, 558 85, 556404, 556136, C07C 4550

Patent

active

059627441

ABSTRACT:
A process comprising subjecting at least one compound containing at least one carbon--carbon double bond or at least one carbon--carbon triple bond, hydrogen and carbon monoxide, to a hydrocarbonylation reaction in supercritical carbon dioxide, in the presence of a Group VIII transition metal catalyst precursor, and a phosphite ligand.

REFERENCES:
patent: 4599206 (1986-07-01), Billing et al.
patent: 4668651 (1987-05-01), Billing et al.
patent: 4737588 (1988-04-01), Billing et al.
patent: 4748261 (1988-05-01), Billing et al.
patent: 4769498 (1988-09-01), Billig et al.
patent: 4885401 (1989-12-01), Billing et al.
patent: 5198589 (1993-03-01), Rathke et al.
patent: 5235113 (1993-08-01), Sato et al.
patent: 5312996 (1994-05-01), Packett et al.
patent: 5360938 (1994-11-01), Babin et al.
patent: 5491266 (1996-02-01), Babin et al.
Organometallics, vol. 14, No. 3, 1995, pp. 1510-1513, Philip G. Jessop, Takao Ikariya, and Ryoji Noyori, "Selectivity for Hydrogenation or Hydroformylation of Olefins by Hydridopentacarbonylmanganese (I) in Supercritical Carbon Dioxide".
Chemtech, pp. 719-723, (1992); Lori Boock, Ben Wu, Concetta La Marca, Michael Klein, Steve Paspek, "Reactions in Supercritical Fluids".
Science, vol. 269, pp. 1065-1069, (1995), Philip G. Jessop, Takao Ikariya, Ryoji Noyori "Homogeneous Catalysis in Supercritical Fluids".
Organometallics, 14, (1995) pp. 3876-3885, James A. Banister, Peter D. Lee and Martyn Poliakoff, "Flow Reactors for Preparative Chemistry in Supercritical Fluid Solution: Solvent-Free" Synthesis and Isolation of Cr(CO).sub.5 (C.sub.2 H.sub.4) and (.eta..sup.5 -C.sub.5 H.sub.5)Mn(CO).sub.2 (.eta..sup. -H.sub.2).
Ind. Eng. Chem. Res. (1977), 36, pp. 4581-4585, Yang Guo and Aydin Akgerman, "Hydroformylation of Propylene in Supercritical Carbon Dioxide".
Organometallics (1992), 11, pp. 585-588, J. W. Rathke, R. J. Klinger and T. R. Krause, "Thermodynamics for the Hydrogenation of Dicobalt Octacarbonyl in Supercritical Carbon Dioxide".
Angew. Chem. Int. Ed. Engl., (1994), vol. 33, No. 14, Gerd Kaupp, Reactions in Supercritical Carbon Dioxide.
Angew. Chem. Int. Ed. Engl. (1997), vol. 36, No. 15, pp. 1628-1630, "Perfluoroalkyl-Substituted Arylphosphanes as Ligands for Homogeneous Catalysis in Supercritical Carbon Dioxide".
J. Am. Chem. Soc. (1996), vol. 118, pp. 344-355, Philip G. Jessop, Yi Hsiao, Takao Ikariya and Ryoji Noyori, "Homogenous Catalysis in Supercritical Fluids: Hydrogenation of Supercritical Carbon Dioxide to Formic Acid, Alkyl Formates, and Formamides".
J. Chem. Soc., Chem. Commun., (1995), pp. 707-708, Philip G. Jessop, Yi Hsiao, Takao Ikariya and Ryoji Noyori, "Methyl Formate Synthesis by Hydrogenation of Supercritical Carbon Dioxide in the Presence of Methanol".
J. Am. Chem. Soc. (1994), vol. 116, pp. 8851-8852, Philip G. Jessop, Yi Hsiao, Takao Ikariya and Ryoji Noyori "Catalytic Production of Dimethylformamide from Supercritical Carbon Dioxide".
Nature, vol. 368, (1994), pp. 231-233, P. G. Jessop, T. Ikariya and R. Noyori "Homogeneous Catalytic Hydrogenation of Supercritical Carbon Dioxide".
Organometallics, (1991), vol. 10, pp. 1350-1355, J.W. Rathke, R.J. Klingler and T. R. Krause, "Propylene Hydroformylation in Supercritical Carbon Dioxide".
Chimia, vol. 47, (1993), No. 493, Manfred T. Reetz, Werner Konen and Thomas Strack, "Supercritical Carbon Dioxide as a Reaction Medium and Reaction Partner".
Science, vol. 265, (1994), pp. 356-359, J. M. Desimone, E. E. Maury, Y.Z. Menceloglu, J.B. McClain, T. J. Romack, J.R. Combes, "Dispersion Polymerizations in Supercritical Carbon Dioxide".
Science, vol. 257, (1992), pp. 945-947, J.M. DeSimone, Zihibin Guan and C. S. Elsbernd, "Synthesis of Fluoropolymers in Supercritical Carbon Dioxide".
J. Am. Chem. Soc., (1995), vol. 117, pp. 8277-8278, Mark J. Burk, Shaoguang Feng, Michael F. Gross and William Tumas "Asymmetric Catalytic Hydrogenation Reactions in Supercritical Carbon Dioxide".
Science, (1994), vol. 263, pp. 203-205, James M. Tanko and Joseph F. Blackert "Free-Radical Side-Cain Bromination of Alkylaromatics in Supercritical Carbon Dioxide".

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