Process for homologating alcohols through the intermediate produ

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568715, 568882, 568883, 568909, C07C 2720

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active

045117438

ABSTRACT:
Process for the homologation of an alcohol wherein a ketal of the alcohol is reacted with hydrogen and carbon monoxide in the presence of a cobalt carbonyl complex and the resultant product is hydrolyzed to yield the aldehyde with one more carbon atom.

REFERENCES:
patent: 4133966 (1979-01-01), Pretzer et al.
patent: 4190729 (1980-02-01), Forster
patent: 4400551 (1983-08-01), Keim et al.
patent: 4401834 (1983-08-01), King
patent: 4424383 (1984-01-01), Cornils et al.
patent: 4429165 (1984-01-01), Wegman
Wender et al., "Organic Synthecol via Metal Carbonyls", vol. 2, Wiley, 1977, pp. 26 to 32.

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