Chemistry: fischer-tropsch processes; or purification or recover – With preliminary reaction to form hydrogen or a carbon oxide – Gaseous oxygen utilized in the preliminary reaction
Patent
1997-07-07
2000-02-15
Killos, Paul J.
Chemistry: fischer-tropsch processes; or purification or recover
With preliminary reaction to form hydrogen or a carbon oxide
Gaseous oxygen utilized in the preliminary reaction
518702, 252373, 60 3902, C07C 2700, C07C 102, F02C 1310
Patent
active
060254033
ABSTRACT:
A process for integration of an autothermal reforming unit and a cogeneration power plant in which the reforming unit has two communicating fluid beds. The first fluid bed is a reformer reactor containing inorganic metal oxide and which is used to react oxygen and light hydrocarbons at conditions sufficient to produce a mixture of synthesis gas, hydrogen, carbon monoxide, and carbon dioxide. The second fluid bed is a combustor-regenerator which receives spent inorganic metal oxide from the first fluid bed and which provides heat to heat the inorganic metal and balance the reaction endotherm, by combusting fuel gas in direct contact with the inorganic metal oxide producing hot flue gas. In preferred embodiments, steam is also fed to the reformer reactor and a catalyst may be used with the inorganic metal oxide.
The cogeneration power plant has a gas turbine equipped with an air compressor and a combustor and in the integration a portion of compressed air is drawn off from the power plant gas turbine air compressor leaving remainder compressed air; the drawn off compressed air is introduced to the combustor-regenerator; the hot flue gas from the combustor-regenerator is mixed with the remainder of the compressed air to produce a recombined gas stream and this recombined gas stream is fed to the combustor of the cogeneration gas turbine power plant.
REFERENCES:
patent: 5624964 (1997-04-01), Cimini et al.
patent: 5799482 (1998-09-01), Marler et al.
Kennedy Clinton Robert
Marler David Owen
Shinnar Reuel
Furr Jr. Robert B.
Keen Malcolm D.
Killos Paul J.
Mobil Oil Corporation
Parsa J.
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