Process for heat-fractionation of organosilanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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203 6, C07F 708

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055457436

ABSTRACT:
An improved process for the heat-fractionation of a mixture comprising an organosilane and a borane or borane forming compound. The improvement comprises the presence of a tertiary organoamine or tertiary phosphorous compound at a concentration sufficient to reduce modification of the organosilane during the heat-fractionation process.

REFERENCES:
patent: 2572302 (1951-10-01), Barry
patent: 2594860 (1952-04-01), Brewer
patent: 2626266 (1953-01-01), Barry
patent: 2775606 (1956-12-01), Wagner et al.
patent: 4411740 (1983-10-01), Flaningam et al.
patent: 5118829 (1992-06-01), Gohndrone
patent: 5321147 (1994-06-01), Chadwick et al.
Wright, J. Organometallic Chemistry 145:307-314 (1978).

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